Heterogeneous Catalysis Unit


The Heterogeneous Catalysis Unit provides support to ICIQ researchers working on heterogeneous catalysis (gas phase reactions catalysed by solids).

To this purpose, it comprises equipment for a wide catalyst characterisation and testing, including textural and reactivity studies, performance of the catalysts for different reactions at different operating conditions and mechanism elucidation of catalytic processes.


To that purpose, some state-of-the-art techniques for the catalysts characterization and testing are available in the unit:

- The TAP (Temporary Analysis of Products) is a cutting edge and not commonly found dynamic technique in which the reactants are pulsed into a catalytic microreactor under high vacuum. A mass spectrometer is located just at the reactor outlet, leading to a time resolution in the sub-milisecond scale. It is one of the most powerful tools in the elucidation of gas-solid heterogeneous reaction mechanisms and pathways. It has shown a great utility not only in the fundamental understanding of catalytic processes, but also in the resolution of problems at an industrial level (e.g. side-reactions minimization in the NH3 oxidation for the production of nitric acid).

- The TPD/R/O (Temperature Programmed Desorption/Reduction/Oxidation) and pulse chemisorption are a group of techniques that allow studying the reactivity or affinity of the catalyst active sites with reactive molecules contained in a gas stream.

Equipment

TAP-2 reactor
Catalytic activity reactor
Physisorption analyzer
TPD/TPR/TPO
Mass spectrometer
Pycnometer
  

Staff

 

DR. MIGUEL GONZÁLEZ HEVIA
UNIT MANAGER
| contact |

    Management and definition of the unit and the equipment.
Development of new applications in close collaboration with the researchers.
Technical support and training of new users.

Seminars

9/8/2010 12:00
Prof. Alan Katritzky
University of Florida (USA)
Some recent developments in the synthesis of peptides and peptide conjugates
9/3/2010 12:00
Prof. Jaume Vilarrassa
Universitat de Barcelona
Catalytic tricks

Publications

Zinc acetates as efficient catalysts for the synthesis of bis-isocyanate precursors
E. Reixach, N. Bonet, F. X. Rius-Ruiz, S. Wershofen, A. Vidal-Ferran
Ind. Eng. Chem. Res. 2010, 49, 6362-6366
Through-space ligand interactions in enantiomeric dinuclear Ru complexes
N. Planas, G. J. Christian, E. Mas-Marzá, X. Sala, X. Fontrodona, F. Maseras, A. Llobet
Chem. Eur. J. 2010, 16, 7965-7968
Interplay between carbon monoxide, hydrides, and carbides in selective alkyne hydrogenation on palladium
M. García-Mota, B. Bridier, J. Pérez-Ramírez, N. López
J. Catal. 2010, 273, 92-102

News & Events

7/9/2010
2010 ICIQ Summer Fellows

Education

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