Heterometallic 3d-4f polyoxometalate derived from the Weakley-type dimeric structure
S. Reinoso, J. R. Galán-Mascarós
Inorg. Chem. 2010, 49, 377-379
Abstract: Polyanion [{Ce(H2O)2}2Mn2(B-α-GeW9O34)2]8− (1) constitutes the first example of a heterometallic 3d−4f cluster related to the Weakley-type dimeric structure, and it contains an unprecedented CeIII2MnIII2O20 rhomblike moiety displaying dominant CeIII−MnIII ferromagnetic interactions.