Golden carousel in catalysis: The cationic gold/propargylic ester cycle
A. Correa, N. Marion, L. Fensterbank, M. Malacria, S. P. Nolan, L. Cavallo
Angew. Chem. Int. Ed. 2008, 47, 718-721
Abstract: Propargylic esters are versatile substrates for Au-based catalysts. However, under typical conditions the starting Au-coordinated propargylic ester 1 is in rapid equilibrium with the gold vinylic carbenoid species 2 and with gold allene species 3. A number of factors dictate which intermediate is lower in energy and which type of products form.
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