Prof. A. Llobet Group

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Oxygen-oxygen bond formation pathways promoted by Ru complexes
Romain, S.; Vigara, L.; Llobet, A.
Acc. Chem. Res. 2009, 42, 1944-1953
 
Water oxidation at a tetraruthenate core stabilized by polyoxometalate ligands: Experimental and computacional evidence to trace the competent intermediates
Sartorel, A.; Miró, P.; Salvadori, E.; Romain, S.; Carraro, M.; Scorrano, G.; Di Valentin, M.; Llobet, A.; Bo, C.; Bonchio, M.
J. Am. Chem. Soc. 2009, 131, 16051-16053.
 
The Ru-Hbpp water oxidation catalyst
F. Bozoglian, S. Romain, M. Z. Ertem, T. K. Todorova, C. Sens, J. Mola, M. Rodríguez, I. Romero, J. Benet-Buchholz,
X. Fontrodona, C. J. Cramer, L. Gagliardi, A. Llobet
J. Am. Chem. Soc. 2009, 131, 15176-15187
 

Oxygen-oxygen bond formation pathways for the Ru-Hbpp water oxidation catalyst
S. Romain, F. Bozoglian, X. Sala, A. Llobet
J. Am. Chem. Soc. 2009, 131, 2768-2769


Molecular catalysts that oxidize water to dioxygen
X. Sala, I. Romero, M. Rodríguez, L. Escriche, A. Llobet
Angew. Chem. Int. Ed. 2009, 48, 2842-2852


Complete mechanism of σ* intramolecular aromatic hydroxylation through O2 activation by a macrocyclic dicopper(I) complex
A. Poater, X. Ribas, A. Llobet, L. Cavallo, M. Solà
J. Am. Chem. Soc. 2008, 130, 17710–17717
 
Ru-Hbpp based water oxidation catalysts anchored into conducting solid supports
J. Mola, E. Mas-Marza, X. Sala, I. Romero, M. Rodríguez, C. Viñas, T. Parella, A. Llobet
Angew. Chem. Int. Ed. 2008, 47, 5830-5832


Heterobimetallic dioxygen activation: Synthesis and reactivity of mixed Cu-Pd and Cu-Pt bis(m-oxo) complexes
J. T. York, A. Llobet, C. J. Cramer, W. B. Tolman
J. Am. Chem. Soc. 2007, 129, 7990-7999


Mechanistic insights into the chemistry of Ru(II) complexes containing Cl and DMSO ligands
J. Mola, I. Romero, M. Rodríguez, F. Bozoglian, A. Poater, M. Solà, T. Parella, J. Benet, X. Fontrodona, A. Llobet
Inorg. Chem. 2007, 46, 10707-10716
 
Fine tuning ligand-receptor design for selective molecular recognition of dicarboxylic acids
A. Arbusé, C. Anda, M. Á. Martínez, J. Pérez-Mirón, C. Jaime, T. Parella, A. Llobet
Inorg. Chem. 2007, 46, 10632-10638
 
Synthesis, structure, redox properties and catalytic activity of new Ru complexes containing neutral or anionic and facial or meridional ligands: An evaluation of electronic and geometrical effects
I. Serrano, X. Sala, E. Plantalech, M. Rodríguez, I. Romero, S. Jansat, M. Gómez, T. Parella, H. Stoeckli-Evans, X. Solans, M. Font-Bardia, B. Vidjayacoumar, A. Llobet
Inorg. Chem. 2007, 46, 5381-5389
 
New synthetic routes towards enantiopure nitrogen donor ligands
X. Sala, A. M. Rodríguez, M. Rodríguez, I. Romero, A. Llobet, A. von Zelewsky, J. Benet-Buchholz
J. Org. Chem. 2006, 71, 9283-9290
 
New Ru complexes containing the N-tridentate “Bpea” and phosphine ligands: The consequences of the meridional vs. the facial geometry
J. Mola, I. Romero, M. Rodríguez, A. Llobet, T. Parella, J. Benet-Buchholz, A. Poater, M. Duran, M. Solà
Inorg. Chem. 2006, 45, 10520-10529
 
Regiospecific C-H activation: Reversible H/D exchange promoted by CuI complexes with triazamacrocyclic ligands
X. Ribas, R. Xifra, T. Parella, A. Poater, M. Solà, A. Llobet
Angew. Chem. Int. Ed. 2006, 45, 2941-2944
 
Can the disproportion of oxidation state III be favored in RuII-OH2/RuIV:O systems?
E. Masllorens, M. Rodríguez, I. Romero, A. Roglans, T. Parella, J. Benet-Buchholz, M. Poyatos, A. Llobet
J. Am. Chem. Soc. 2006, 128, 5306-5307
 
Catalytic ability of a cationic Ru(II) monochloro complex for the asymmetric hydrogenation of dimethyl itaconate and enamides
I. Serrano, A. Llobet, M. Rodríguez, I. Romero, J. Benet-Buchholz, T. Parella, J. Campelo, D. Luna, J. Marinas
Inorg. Chem. 2006, 45, 2644-2651
 
Atropisomeric discrimination in new RuII complexes containing the C2-symmetric didentate chiral phenyl-1,2-bisoxazolinic ligand
X. Sala, E. Plantalech, A. Poater, M. Rodríguez-Pizarro, I. Romero, M. Solà, A. Llobet, S. Jansat, M. Gómez, H. Stoeckli-Evans, J. Benet-Buchholz
Chem. Eur. J. 2006, 12, 2798-2807
 
Fine-tuning the electronic properties of highly stable Cu(III) complexes containing monoanionic macrocyclic ligands
X. Ribas, R. Xifra, A. Llobet, T. Daniel, P. Stack, A. Poater, M. Duran, M. Solà, J. Benet-Buchholz, B. Donnadieu, J. Mahía, T. Parella
Chem. Eur. J. 2005, 11, 5146-5156
 

Tren-based tris-macrocycles as anion hosts. Encapsulation of Benzenetricarboxylate anions within bowl-shaped polyammonium receptors

C. Bazzicalupi, A. Bianchi, A. Bencini, L. Borsari, C. Giorgi, B. Valtancoli, C. Anda, A. Llobet
J. Org. Chem. 2005, 70, 4257-4266
 
A new Ru complex catalyst capable of catalitically oxidizing water to molecular dioxygen
C. Sens, I. Romero, M. Rodríguez, A. Llobet, T. Parella, J. Benet-Buchholz
J. Am. Chem. Soc. 2004, 126, 7798-7799

Seminars

9/8/2010 12:00
Prof. Alan Katritzky
University of Florida (USA)
Some recent developments in the synthesis of peptides and peptide conjugates
9/3/2010 12:00
Prof. Jaume Vilarrassa
Universitat de Barcelona
Catalytic tricks

Publications

Zinc acetates as efficient catalysts for the synthesis of bis-isocyanate precursors
E. Reixach, N. Bonet, F. X. Rius-Ruiz, S. Wershofen, A. Vidal-Ferran
Ind. Eng. Chem. Res. 2010, 49, 6362-6366
Through-space ligand interactions in enantiomeric dinuclear Ru complexes
N. Planas, G. J. Christian, E. Mas-Marzá, X. Sala, X. Fontrodona, F. Maseras, A. Llobet
Chem. Eur. J. 2010, 16, 7965-7968
Interplay between carbon monoxide, hydrides, and carbides in selective alkyne hydrogenation on palladium
M. García-Mota, B. Bridier, J. Pérez-Ramírez, N. López
J. Catal. 2010, 273, 92-102

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7/9/2010
2010 ICIQ Summer Fellows

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